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Monday, August 10, 2009

Energy changes and chemical kinetics


Chemical reactions are typically accompanied by energy changes. The equation for the synthesis of ammonia from its elements is N 2 + 3 H 2 → 2 NH 3 , but that reaction takes place only under very special conditions—namely at a high temperature and pressure and in the presence of a catalyst. Energy changes that occur during chemical reactions are the subject of a field of science known as thermodynamics.
In addition, chemical reactions are often a good deal more complex than a chemical equation might lead one to believe. For example, one can write the equation for the synthesis of hydrogen iodide from its elements, as follows: H 2 + I 2 → 2 HI. In fact, chemists know that this reaction does not take place in a single step. Instead, it occurs in a series of reactions in which hydrogen and iodine atoms react with each other one at a time. The final equation, H 2 + I 2 → 2 HI, is actually no more than a summary of the net result of all those reactions. The field of chemistry that deals with the details of chemical reactions is known as chemical kinetics. Read more:

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